Decarbonisation Technology May 2025 Issue

which allows the feasible continuation of operations with an economically attractive scheme. The new configuration includes the following elements that are the basis of a feasible, technically sound, and financially beneficial transition: • The production of the existing, traditional refinery is reduced to a level of 80% in order to continue production, with the production of e-fuels making up the remaining 20% for an acceptable investment. • A methanol-dimethyl ether (DME)-oligomerisation unit, which consumes CO 2 captured from the hydrogen

CO 2 emiss i ons (MTPA)

Unit

Description

Capacity (kBPD)

CDU1 HVU1 LNHT HNHT HCU HTD ISOM

Crude atmospheric distillation unit

80 33 34

90,242 52,534 166,679 85,070 255,209 101,644 229,778 166,751 32,326 -576,000

Vacuum distillation unit VGO hydrocracking unit

Light naphtha hydrotreating unit Heavy naphtha hydrotreating unit Distillates hydrotreating unit Light naphtha isomerisation unit Heavy naphtha reforming unit

5

13

8 5

REFOR SATGAS

12

Saturated gas unit Synthetic fuel unit Standard diesel Total process units Jet A1

4

SFU

Jet

3.615 1.916

604,233 503,496 1,107,729

HMU

Hydrogen production unit

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Hybrid case total CO 2 emissions

Table 2 Hybrid case – unit capacity and CO2 emissions from each process unit

manufacturing unit (HMU) (‘blue’ hydrogen unit of the refinery), as well as an electrolysis unit to produce ‘green’ hydrogen is considered in the analysis. See new refinery process configuration online: bit.ly/4cHVcsW The new configuration for the refinery provides the following interesting insights: • Overall CO 2 by-product is reduced, as the refinery load has been reduced to 80%. • The CO 2 from the traditional hydrogen reformer

unit (otherwise one of the main CO 2 emitting units in any refinery) is captured and used. • The shortfall in jet fuel and diesel from the load reduction on existing units is now produced by the synthetic fuels unit, using the captured CO 2 combined with low carbon intensity blue and green hydrogen. The criteria for sizing the synthetic fuels unit (SFU) was to cover the production of jet fuel with SAF and use 100% of the CO 2 captured from the HMU. The new configuration for the refinery provides the unit capacity and products slate, as seen in Table 2 . The emissions of CO 2 now have been reduced in a very interesting range.

120%

100%

80%

60%

2,500,000

40%

2,000,000

20%

1,500,000

0

1,000,000

500,00

Base case

Load reduction no synthetic

Load reduction synthetic

0

Base case Load reduction no synthetic

Load reduction synthetic

Figure 5 Comparison of products from the base and hybrid cases (before and after the synthetic fuels capacity is added)

Figure 6 Comparison of CO 2 emissions from the base and hybrid cases

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