Decarbonisation Technology - May 2024 Issue

Isomerate

ISOM

LSR

CDU & VDU

NHTU

HTLN2

Reformate

CCRU

HSR

C LPG

HTLN1

ETBE

HTH naphtha

Gasoline 95

HTHN2

Kero distil

CC

Gasoline 93

SR d iesel

DHT naphtha DHT k ero DHT d ist

Kerosene

HDS

LVGO

Diesel

HVGO Vac r esid

HF Oil

Blender

NAPHTL NAPHTH

HC ligh t naphtha HC hea vy naphtha HC k ero HC d iesel

HCU

Asphalte

Coker HN LCGO HCGO

DCU

Ind. diesel

Coke

CO

Blue H unit

H

e-SAF

H

e-fuel

e- d iesel

H to process units

Figure 4 Optional case. Hybrid refinery configuration scheme

The captured (or ‘sequestrated’) CO 2 is subsequently used inside the refinery as feedstock for the production of synthetic fuels. The amount of CO 2 generated in the HPU is: HPU unit capacity 95,625 TPA CO 2 generated (CO 2 HPU): 900,000 TPA All the CO 2 of the HPU will be considered as sequestrated.  Green hydrogen generation The SMR equipped with CO 2 capture produces blue hydrogen for use in refinery processes such as hydrotreaters and the hydrocracking unit. Additional hydrogen capacity is needed to ensure sufficient feedstock for the synthetic fuels unit. A water electrolyser is included with the

following criteria used to determine the capacity: • Total hydrogen required in the conventional hydroprocessing units, plus the hydrogen required in the e-SAF and e-diesel units, minus the hydrogen reduction resulting from the change to substitute a percentage of synthetic fuels in place of regular kerosene and diesel. • The green hydrogen unit is sized once the synthetic fuels are sized for the total consumption of the CO 2 previously captured.  Synthetic fuels production The combination of blue and green hydrogen plus the captured carbon monoxide is used as feedstock to produce synthetic e-SAF and e-diesel (see Figure 4 ).

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