Decarbonisation Technology - May 2023 Issue

Safety gas analysis H in O

Safety gas analysis O in H

Condensate trap

O

Control valve

Cooling water

Demister

Demister

Catalytic de-oxo unit

Cooling water

Cooling water

Feed water pump

Gas/lye phase separator

Purier

Water feed

Regenerative twin bed dryer

Gas/lye phase separator

KOH management

Lye tank

Control valve

Pressurised alkaline electrolysis stack

+

Cooling water

H

Gas purity analysis

Recirculation pump

Filter

DC

Electricity

Fresh KOH

AC

Rectier Transformer

Figure 3 Pressurised alkaline electrolysis process

scheme. To put this into context, the power management system involving the transformer and rectifier to convert grid, wind, or hydropower to be suitable DC electricity for the electrolyser would be around 20%. Cooling water and balance of plant power Electrolysers are approximately 70% efficient when they convert power to hydrogen. The

wasted power generates heat which is generally dissipated on a cooling tower. A typical cooling tower will need about 2% of the daily recirculated cooling water volume to be topped up due to evaporation losses (see Figure 3 ). The pumps that recirculate the cooling water, drive the cooling tower fans, and recirculate the electrolyte around alkaline electrolysers all consume power. However, the power demand

Condenser

Water feed

Preheater

Steam superheater

Syngas CO/H

Water outlet

Sweep air feed

Oxygen heat recovery

Vapouriser

Compressor

Air & oxygen exhaust

Expander

SOE stack + –

CO feed

Rectier

Transformer

AC

Electricity

DC

Figure 4 Solid oxide CO-electrolysis process for syngas generation

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