Decarbonisation Technology - August 2023 Issue

Crude and vacuum stack capture

Crude and vacuum electric heating

Base emissions Tonnes/hour CO captured Boiler increase Scope 2 increase

Base emissions Tonnes/hour 221 Stack CO avoided -37 Scope 2 increase 119

221 -33

Carbon capture

8

11

Net change

82

Net change

-14 207

Finding the optimal balance

New emissions

303

New emissions

(No fuel gas aring)

Crude and vacuum SMR H ring

Base emissions Tonnes/hour 221 Stack CO avoided -3 7 Boiler change Scope 2 increase -3 0 50 Additional SMR CO

Hydrogen ring

Electrication

Net change

10

New emissions

231

Figure 3 Balancing Scopes 1 and 2 emissions

from the facility. This can be achieved by either providing emission-free energy sources such as zero-carbon intensity hydrogen and electricity or capturing the resulting emissions before they are released into the air via carbon capture. Misleading internal approaches Here is the catch. By purchasing more electricity from the grid to energise modified fired heaters, the increase in Scope 2 emissions outweighs the decrease in Scope 1 emissions, as shown in Figure 3 . This scenario leads to higher product carbon intensities. Using hydrogen-fired heaters and boilers also raises CO₂ emissions due to the fossil energy required to operate the steam methane reformer (SMR) combined with the CO₂ emissions produced by the reaction. If natural gas is purchased and the SMR is used to produce the necessary hydrogen, CO₂ emissions will increase. Even with systems such as amine absorption in place, only half of the expected CO₂ may be captured. This is By purchasing more electricity from the grid to energise modified fired heaters, the increase in Scope 2 emissions outweighs the decrease in Scope 1 emissions

due to the extra boiler load required for amine regeneration steam and the electricity needed for compressing the captured CO₂. After energy efficiency improvements are completed, the ‘going-it-alone’ strategy faces fast-diminishing returns. To further reduce emissions, solutions from outside the facility gates must be sought. This approach incorporates new low-carbon energy sources like wind and solar power and uses low- carbon hydrogen produced from electrolysers that employ ‘green’ electricity. Another option includes capturing CO₂ emissions and either using them as chemical process feedstocks or sequestering them in the earth’s crust. Solutions must be explored outside the facility’s boundary. Outside-the-box approaches Carbon capture (CC) is a mature technology that carries low risk and reliable operations. The downside of the approach is that these units can require large areas of plot space near the emissions source because of the size and cost of the towers and ducting. Often, that plot space is unavailable. Furthermore, they are capital intensive. For instance, recent projects aiming to capture 1 million tonnes of CO₂ per year cost about USD 500 million, and that is only the beginning. Finding a destination for the captured CO₂ is equally as important to prevent its re-entry into the atmosphere.

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