Decarbonisation Technology - August 2023 Issue

Parameter

Spec

Test run result

LPG recovery, %

88 (min)

89.1

LPG quality C 2 , mol%

2.0 (max) 94.0 (min) 4.0 (max) 1.0 (max)

0.0

Ranate

Extract

C 3 , mol% C 4 , mol% C 5 , mol%

98.2

1.8

nil

Table 1 GT-LPG Max test run results

otherwise burned, which led to a high carbon footprint operation. By using GT-LPG Max technology, this plant was able to accomplish two goals: minimise the off-gas that is routed to the treating system and produce an on-spec propane product. Following completion of the performance test run, the new unit was able to achieve a higher purity product at recovery greater than design (see Table 1 ). Additionally, by removing a value component that otherwise went to flare, this single project led to a decrease in CO 2 emissions of 260,000 kta. Higher octane gasoline with GT-BTX PluS GT-BTX PluS is an extractive distillation process that uses a solvent to alter the relative volatility of components being separated. In a mixture containing aromatics and non-aromatics, the relative volatility of the non-aromatic

Rich solvent

Lean solvent

components is enhanced over the aromatic components in the presence of the solvent. The process consists of only two major columns: an extractive distillation column (EDC) and a solvent recovery column (SRC), as shown in Figure 3 . The solvent recirculates between the two columns to extract the aromatics and sulphur components while rejecting the non- aromatics, including olefins, which form the raffinate. The solvent used in the GT-BTX PluS process is a proprietary blend from Sulzer called Techtiv. Figure 3 Schematic of the GT-BTX PluS extractive distillation and solvent recover columns

Benzene concentrate from reformate

O - gas

Naphtha splitter

LCN

SHU

FCC naphtha

Ranate

New GT- BTX Plu S

O - gas

Benzene

Stabiliser

H

Extract

BZ column

HDS

HCN

MCN splitter

Treated FCC gasoline

H

Figure 4 Process flow diagram of existing gasoline hydrotreater (grey) that has been retrofitted with GT-BTX PluS (green)

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