Refining India 2024 Conference Newspaper

refining india 2024

Fueling success: SAF route to aviation sustainability

Leigh Abrams Honeywell UOP

Honeywell’s (FT) Unicracking™ technology converts FT liq- uids and waxes from agricultural, munic- ipal, and forestry waste, in addition to biogas and CO2 combined with H2 to FT Synthetic Paraffinic Kerosene (FT-SPK), which is a form of ASTM D7666-approved SAF. Fischer-Tropsch Honeywell UOP was recently awarded by DG Fuels with the largest announced FT-hydrocracker unit in the world to date, producing 13,000 BPD of SAF. The plant has an expected start-up in 2028 and will be located in Louisiana, USA. This also marks the first joint project with Johnson Matthey and BP’s co-developed Fischer Tropsch (FT) CANS™ technology, serving as a foundation for future joint FT+ hydroc- racking projects. For refiners, FT-Unicracking provides an excellent opportunity for repurposing exist- ing assets to take advantage of the SAF/ fossil kerosene spread. Hydroprocessing units can cost-effectively be revamped to 100% FT-Unicracking units or con- verted via a staged investment by first co- processing, followed by eventual 100% FT-Unicracking. One of the key benefits of FT liquids and waxes compared to other renewable/lower carbon intensity feedstocks is that these feeds are highly paraffinic and do not con- tain contaminants like chlorides, sulphur, nitrogen, and high amounts of oxygenates and metals. This is a technology pathway with a high Technology Readiness Level, in combination with a high carbon efficiency and a low, zero or even carbon-negative SAF product, resulting in a high bankabil- ity score. References 1 www.ourworldindata.org/co2-emissions- from-aviation 2 www.europarl.europa.eu/news/de/press-room/ 20230424IPR82023/fit-for-55-parliament-and- council-reach-deal-on-greener-aviation-fuels 3 www.icao.int/environmental-protection/ CORSIA/Documents/CORSIA%20States%20 for%20Chapter%203%20State%20Pairs_4Ed_ rev_web.pdf 4 www.icao.int/environmental-protection/ CORSIA/Pages/CORSIA-Eligible-Fuels.aspx 5 www.icao.int/environmental-protection/pages/ SAF.aspx 6 www.theicct.org/ira-unlock-green-hydrogen- jan23 7 www.moei.gov.ae/assets/download/ 9b4bf8a9/​UAE_National_SAF_Roadmap.pdf.aspx 8 www.biofuelsdigest.com/bdigest/2023/09/16/ sustainable-aviation-fuel-challenges-of-scale

Aviation accounts for 1.9% of overall greenhouse gas (GHG) emissions, making it an important pain point for policymakers and consumers alike in the drive towards decarbonisation.¹ Climate action is becom- ing more codified by governmental initia- tives and regulations. For example, the European Council released its ReFuelEU Aviation rules as part of the ‘Fit for 55’ package, aiming to increase the sustainable fuels share at EU airports from a minimum of 2% in 2025 to 70% by 2050, with an additional sub-target for eSAF of 1.2% by 2030 and 35% by 2050.² The Carbon Offsetting and Reduction Scheme for International Aviation (CORSIA), which is part of the United Nations’ International Civil Aviation Organization (ICAO), stipulates SAF as one of its eligi- ble measures.³ , ⁴ Following technical analy- sis of lower-carbon aviation fuels, ICAO has stated that “SAF has the greatest potential to reduce CO₂ emissions from International Aviation”.⁵ Investment targets The US’s Inflation Reduction Act (IRA) reduces the cost of clean hydrogen pro- duction by almost half and contributes to almost $369 billion dollars being made available to address energy security.⁶ Echoing the EU’s ‘Fit for 55’ package, the UAE’s Minister of Energy and Infrastructure has set a target of producing 700 mil- lion litres of SAF annually by 2030, and sees positive incentives as a critical tactic for achieving that growth.⁷ Meanwhile, in 2021, the Biden Administration announced its Sustainable Aviation Fuel Grand Challenge for the US aviation fuel supply sector to produce at least three billion gal- lons of SAF per year by 2030 and 35 billion gallons of SAF per year by 2050.⁸ Renewable jet fuel The Ecofining™ process for renewable jet fuel is based on refinery hydroprocessing technology. The process produces a bio- synthetic paraffinic kerosene (bio-SPK) or renewable diesel, which is then blended with standard jet fuel for use in flight. With incentives available today in the US, even marginal improvements in distillate yield provide a substantial economic benefit.

Renewable Naphtha

Ecofining ™ & UOP Renewable Jet Fuel Process

Inedible

Sustainable Aviation Fuel (SAF) Renewable Diesel (RD)

UOP Distillate Unionfining™ Process

Partial SAF Partial RD

Vegetable oils

Animal fats

Greases

Algal oil

Partial renewable LPG Partial renewable gasoline

UOP FCC Coprocessing

Petroleum

VGO Inedible FOGs

Partial RD

RFO for Heating/Power

Envergent RTP® (Pyrolysis)

Biomass

Renewable Naphtha RD and renewable Marine SAF

Hydrotreating/ Upgrading

Gasication

Fis c her - Tropsch + UOP FT-Unicracking™

SAF eSAF (when green H used)

H

CO

Fis c her - Tropsch + UOP FT-Unicracking™

+

UOP Ethanol to Jet Process

Ethanol

SAF

Figure 1 Route to SAF production

called e-fuels, combining renewably manu- factured green hydrogen with CO₂ to pro- duce eMethanol. As a highly integrated design that can process flexible feedstocks using commercially proven processes, the technology results in high-yield eSAF pro- duction while reducing GHG emissions by 88% compared to conventional jet fuel.¹¹ Since 2011, millions of gallons of SAF have been produced using Honeywell UOP technology that meets ASTM D7566 spec- ifications. This includes the fuel used for the world’s first transatlantic flight powered entirely by SAF.¹² SAF can be produced from a variety of sustainable feedstocks, includ- ing vegetable oils, animal fats, non-food- based fats, second-generation feedstocks such as camelina, jatropha and algae, and low-carbon- intensity alcohols. GHG reduction by 70% When blended up to 50% with petroleum- based jet fuel, SAF offers significant advan- tages over traditional fuel, such as with its higher energy density in flight allows air- craft to fly farther on less fuel. That means it offers a drop-in replacement fuel that requires no changes to aircraft technology or fuel infrastructure.¹³

At a 10,000 BPD feed rate, for exam- ple, a 1 wt% yield advantage is worth approximately $6 million in profits annually. Moreover, our experience with many types of sustainable feedstocks means we can guarantee catalyst cycle lengths based on actual operating data. The value of avoid- ing a five-day shutdown for catalyst reload is worth approximately $8 million in revenue for a 10,000 BPD unit.⁹ Single-stage Ecofining technology, ena- bling renewable diesel production, is ideal for refinery retrofits. A retrofit initiative typ- ically costs 50-70% less than a greenfield project and can be completed in an aver- age of 12-18 months, setting the stage for a straightforward expansion to two-stage processing for renewable jet fuel, which can be implemented later.¹⁰ With these types of assets, the Honeywell UOP ethanol-to- jet (ETJ) technology has been developed for ethanol producers looking for diversification to satisfy the needs of the aviation market. Low-carbon SAF eFining™ technology is a methanol-to-jet fuel (MTJ) processing technology that can convert eMethanol to eSAF reliably and at scale. eSAF belongs to a class of fuels

9 www.uop.honeywell.com/en/industry- solutions/renewable-fuels/ecofining 10 www.pmt.honeywell.com/learnmore/ ecofining/ebook

11 www.honeywell.com/us/en/press/2023/05/ honeywell-introduces-uop-efining-technolo- gy-for-new-class-of-sustainable-aviation-fuel 12 www.worldenergy.net/gulfstream 13 www.uop.honeywell.com/en/industry- solutions/renewable-fuels/honeywell- sustainable-aviation-fuel Contact: Daniela.Delgado@Honeywell.com

7

Powered by