Revamps 2025 Issue

Case Study 2: Naphtha splitter revamp at a South Asian refinery

Case study 3: Naphtha splitter revamp at a South Asian refinery

Conventional

Middle DWC

Conventional

Middle DWC

design

design

design

design

(Naphtha splitter

(only Naphtha

Feed rate, kg/hr

330,000 180,000

330,000 160,000

I and II) 308,000 105,400

Splitter I) 308,000 109,700

Side draw rate, kg/hr

Feed rate, kg/hr

Side cut D86 (IBP/FBP), °C

106 to 191

111 to 180

Side cut C 8 /C 9 rate, kg/hr Side cut C 8 /C 9 content, wt% Side cut C 8 /C 9 recovery, %

Overla p (middle naphtha D86 95% - heavy naphtha D86 5%), °C

63.9

66.5

55

8

95

98

Ene rgy savings, %

25%

a

Light naphtha

b

Light naphtha

Heart cut naphtha

Feed

Middle naphtha

Feed

Heart cut naphtha

Heavy naphtha 2

Heavy naphtha

Figure 4 Retrofitted naphtha splitter with a middle DWC

original column struggled to deliver the required separation between light, middle, and heavy naphtha, resulting in off- spec products and operational challenges such as exces- sive C₆ and C1₀+ in the middle cut. These issues threatened catalyst life and product yields in downstream units. Conventional upgrade strategies, including reboiler duty shifts and feed location changes, proved insufficient, and installing a second column was ruled out due to high capital costs. To address these chal- lenges, the column was successfully upgraded using a mid- dle DWC configuration within a tight 20-day turnaround. The revamp involved replacement of the conventional trays by high-performance ones, custom-designed DWC internals, changes to the side draw location, and a new reboiler with minimal changes to the control system. Post- revamp, the column achieved a sharp 25°C gap between light and heavy naphtha and reduced the overlap between middle and heavy cuts from 55°C to just 8°C. The revamped unit delivered improved product quality and operational stability, running reliably for more than seven years without major issues. This transformation demon- strated the effectiveness of DWC technology in achieving high-performance separation within existing infrastructure. In another case study, a South Asian refinery originally used two separate distillation columns to fractionate naph- tha into light, heart-cut (C8 /C 9 ), and heavy naphtha to meet stringent product quality requirements (see Figure 5 ). The first column received feed from the depentaniser and produced preliminary light, heart-cut, and heavy naphtha Figure 5 Upgrade of a naphtha splitter into a DWC: (a) Naphtha splitter I revamped to DWC, (b) Naphtha splitter II idled

subsequently processed in a reformate splitter to isolate C 6 hydrocarbons. These C 6 components, which include ben- zene, are then sent to the benzene extraction unit for fur- ther purification. Each of these separation steps presents opportunities for DWC integration to improve separation efficiency, reduce energy use, and increase product value. Naphtha splitter revamp opportunity A key opportunity for DWC implementation lies in revamp- ing the naphtha splitter for octane boost, where naphtha is split into an iC₅-rich top product, a normal paraffins-rich C₅-C₆ middle cut, and a C₇+ bottom product (see Figure 3 ). This approach raises isomerate octane, increases ISOM unit capacity by maximising normal paraffins in the feed, and delivers a 20-30% energy saving. A case study from a Middle East refinery highlights the performance improvements achieved by converting a con- ventional naphtha splitter into a middle-wall DWC (Figure 3). The DWC design significantly enhanced the separa - tion of iC₅ and nC₅ components, improving iC₅ purity in the overhead from 70% to 85% and reducing nC₅ con - tamination. Additionally, the side draw saw improved nC₅ concentration, while maintaining low C₇+ and C₆ content in undesired fractions. Most notably, the revamp delivered a 30% reduction in energy consumption, underscoring the thermodynamic efficiency of the DWC configuration. In a separate case study in a South Asian refinery, a con - ventional naphtha splitter at an FCC unit was repurposed to meet more demanding product specifications, particu - larly for the middle naphtha cut, which was redirected to downstream aromatics recovery units (see Figure 4 ). The

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Revamps 2025

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