PTQ Q4 2026 Issue

1.0

LT disturbance start Probability Threshold Early detection

0.8

There was increase in probability 30 minutes before LT going bad and 6 hours before rst instance of reboiler instability

One spike in probability at 08:00 on Trip-previous -d ay , which was 8 hours before LT malfunction

0.6

08:00

16:00

0.4

0.2

0.0

06-08 00

06-08 06

06-08 12

06-08 18

06-09 00

06-09 06

06-09 12

06-09 18

06-10 00

06-10 06

Timestamp

Figure 4 Predicted upset probability highlighting early detection capability

entire dataset, the model showed its true power. It gener- ated intermittent spikes in upset probability starting from a day or week ago, well before the incident. Crucially, Figure 4 showed a significant probability spike at 08:00 on the day of upset, around eight hours before the LT began to malfunction, and a continuous increase in probability from 15:30, providing hours of potential warning. The confusion matrix, as shown in Table 1 , indicates the model performance, where it captured all anomalies, 100% correct anomaly prediction and only 0.02% of the normal data were wrongly identified as anomalous. Model 2: Dynamic mass balance and level prediction This model was developed specifically to counteract the pri - mary failure mode of the incident: the unreliable LT without redundancy. It uses first principles of mass balance to pro - vide an independent, calculated value for the column’s liquid inventory and level. • Methodology: The model establishes a system boundary around the C 3 splitter column and calculates a real-time mass balance:

Model accuracy on validation dataset

Pred normal

Pred anomalous

Actual normal

88,060

18

Actual anomalous

0

465

Table 1

• Data preparation and training:  Data fetching: Historical data was extracted from the plant’s data historian at a two-minute resolution.  Event labelling: The data was labelled based on the known incident. The period from the LT malfunction (16:00 Trip-previous-day) to the HPC trip (07:36 hrs Trip-day) was labelled as ‘bad’ (Class 1). All other periods of normal operation were labelled as ‘good’ (Class 0).  Class imbalance: This resulted in a highly imbalanced dataset, with far more ‘good’ data than ‘bad’ data (a ratio of approximately 100:0.7). To prevent the model from being biased towards the majority class, the ‘good’ data was down-sampled by averaging it over 15-minute intervals, bringing the ratio to a more manageable 9:1.

Accumulation = Mass_In - Mass_Out

Where: • Mass_In: Calculated from the feed flow meter.

 Train-test split: The bal- anced dataset was split into a 70% training set and a 30% testing set to evaluate the model’s performance on unseen data. • Performance: The logistic regression model demon- strated exceptional perfor- mance, achieving perfect scores (1.0) for precision, recall, and F1 score on both the training and test datasets. This indicated that it could perfectly distinguish between the normal and upset condi- tions present in the historical data (see Figure 4 ). When validated against the

Trendline of mass balance closure

1.15

1.10

1.053

1.05

Mean: 1.011

1.00

0.968

0.95

2stdev 1stdev Mass balance closure

0.90

0.85

2024-01

2024-02

2024-03

2024-04

2024-05

2024-06

2024-07

2024-08

Timestamp

Figure 5 Historical mass balance closure

61

PTQ Q4 2026

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